Desain Elektroda Selektif Ion Untuk Logam Timbal (II) (ESI-Pb (II)) Menggunakan Ionofor p-t-Butilkaliks [4] Arena

Awaluddin IP, Abd. Wahid Wahab, Maming Maming


This study aims to determine the design pattern ESI-Pb (II) with ionophores pt-butilkaliks [4] arena. In this study, ion selective electrode is designed for the determination of lead (II) (ESI-Pb (II)) using ionophores pt-butilkaliks [4] arenas and diimmobilasi on a matrix of polyvinyl chloride (PVC) in the membrane ESI-Pb (II). The results showed a design pattern ESI-Pb (II) with ionophores pt-butilKaliks [4] arena is best to ESI with membrane composition (% by weight), namely: (pt-butilKaliks [4] arena: KTCPB: DOS: PVC) is 3 : 2: 60: 35 with the Nernst factor: 27.61 mV / decade


Ion Selective Electrode; Ionophores; Ion Pb2+; Potentiometry

Full Text:



Bailey. P L., 1976, Analysis with ion-selective electrodes, Heyden and Sons, New York.

Buhlmaa, P., Pretsch, E., Bakker, E.,1998. Carier-based Ion Selective Electrodesand Bulk Optodes (2). Ionophoresfor Potentiometric and Optical Sensor, Chem. Review, 98, 1593-1687.

Cunningham, L. 1986. Coated Wire Ion Selective Electrodes. Anal. Chim. Acta. 180, 271–279.

Cha, G. S., Liu, Meyerhoff, M. E., Cantor, H. C., Midgley, A. R., Goldberg, H. D., and Brown, R. B. 1991. Electrochemical Performance, Biocompatibility, and Adhesion of New Polimer Matrices for Solid State Ion Sensors. Anal. Chim. Acta. 63, 1665 – 1672.

Fardiaz,S., 1995. Polusi Air dan Udara, Penerbit Kanisius, Yogyakarta, Heryando, P., 2004. Pencemaran Dan Toksikologi Logam Berat. PT Rineka Cipta. Jakarta.

Gutsche, C.D., 1998, Calixarenes Revisited, Monograph in Supramolecular Chemistry, Royal Society of Chemistry, Cambridge.

Wahab, A. W. 2006. Studi Kinerja Sensor Potensiometrik: Elektroda Selektif Ion Zn(II), Cd(II), dan Hg(II) dengan Ionofor DBDA 18C6 Terhadap Analisis Pencemaran Sedimen Laut Kawasan Pesisir Pantai Makassar. Disertasi. Program Pascasarjana Universitas Hasanuddin, Makassar.

Zolotov, Y, A., 1997, Macrocyclic Compound in Analytical Chemistry, John Wiley & Sons, Inc., New York, 143,229,306,309.



  • There are currently no refbacks.

Al-Kimia has been indexed in :

See Google Scholar Profile for Al-Kimia by clicking here.



Supported By:

Creative Commons License All Publication by Al-Kimia are licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

Visitor Number: StatCounter - Free Web Tracker and Counter View Al-Kimia Stats

Al-Kimia, p-ISSN : 2302-2736, e-ISSN : 2549-9335

Office Address:

Faculty of Science and Technology, Universitas Islam Negeri Alauddin Makassar, Indonesia
Jl. H. M. Yasin Limpo No. 36 Samata, Gowa, Sulawesi Selatan

Contact Person: +6285-286-545-307,