Desain Elektroda Selektif Ion Untuk Logam Timbal (II) (ESI-Pb (II)) Menggunakan Ionofor p-t-Butilkaliks [4] Arena

  • Awaluddin IP Jurusan Kimia, Fakultas Sains dan Teknologi, UIN Alauddin Makassar
    (ID)
  • Abd. Wahid Wahab
  • Maming Maming

Abstract

This study aims to determine the design pattern ESI-Pb (II) with ionophores pt-butilkaliks [4] arena. In this study, ion selective electrode is designed for the determination of lead (II) (ESI-Pb (II)) using ionophores pt-butilkaliks [4] arenas and diimmobilasi on a matrix of polyvinyl chloride (PVC) in the membrane ESI-Pb (II). The results showed a design pattern ESI-Pb (II) with ionophores pt-butilKaliks [4] arena is best to ESI with membrane composition (% by weight), namely: (pt-butilKaliks [4] arena: KTCPB: DOS: PVC) is 3 : 2: 60: 35 with the Nernst factor: 27.61 mV / decade

Downloads

Download data is not yet available.

References

Bailey. P L., 1976, Analysis with ion-selective electrodes, Heyden and Sons, New York.

Buhlmaa, P., Pretsch, E., Bakker, E.,1998. Carier-based Ion Selective Electrodesand Bulk Optodes (2). Ionophoresfor Potentiometric and Optical Sensor, Chem. Review, 98, 1593-1687.

Cunningham, L. 1986. Coated Wire Ion Selective Electrodes. Anal. Chim. Acta. 180, 271–279.

Cha, G. S., Liu, Meyerhoff, M. E., Cantor, H. C., Midgley, A. R., Goldberg, H. D., and Brown, R. B. 1991. Electrochemical Performance, Biocompatibility, and Adhesion of New Polimer Matrices for Solid State Ion Sensors. Anal. Chim. Acta. 63, 1665 – 1672.

Fardiaz,S., 1995. Polusi Air dan Udara, Penerbit Kanisius, Yogyakarta, Heryando, P., 2004. Pencemaran Dan Toksikologi Logam Berat. PT Rineka Cipta. Jakarta.

Gutsche, C.D., 1998, Calixarenes Revisited, Monograph in Supramolecular Chemistry, Royal Society of Chemistry, Cambridge.

Wahab, A. W. 2006. Studi Kinerja Sensor Potensiometrik: Elektroda Selektif Ion Zn(II), Cd(II), dan Hg(II) dengan Ionofor DBDA 18C6 Terhadap Analisis Pencemaran Sedimen Laut Kawasan Pesisir Pantai Makassar. Disertasi. Program Pascasarjana Universitas Hasanuddin, Makassar.

Zolotov, Y, A., 1997, Macrocyclic Compound in Analytical Chemistry, John Wiley & Sons, Inc., New York, 143,229,306,309.

Published
2015-01-30
How to Cite
IP, A., Wahab, A. W., & Maming, M. (2015). Desain Elektroda Selektif Ion Untuk Logam Timbal (II) (ESI-Pb (II)) Menggunakan Ionofor p-t-Butilkaliks [4] Arena. Al-Kimia, 3(1), 24-33. https://doi.org/10.24252/al-kimia.v3i1.1658
Section
Article
Abstract viewed = 862 times