Sintesis Heksa-p-tert-Butilheksaesterkaliks[6]Arena dari p-tert-Butilkaliks[6]Arena

  • Nasriadi Dali Jurusan Kimia, FMIPA, Universitas Halu Oleo
    (ID)
  • Abd. Wahid Wahab
  • Firdaus Firdaus
  • Maming Maming

Abstract

A research has been done to synthesize hexa-p-tert-butylhexaestercalix[6]arene using p-tert-butylcalix[6]arene as a starting material. The synthesis was carried out by esterifying p-tert-butylcalix[6]arene. Synthesis products were identified and characterized by melting point, TLC, FTIR, 1H-NMR, and 13C-NMR spectrometers. Synthesis products was obtained a white solid powder (68.45% recovery), melting point 349-351 °C, TLC (SiO2, ethanol: ethyl acetate = 1: 1 v/v, Rf = 0.90). The results of the analysis  of synthesis products with FTIR, 1H-NMR, and  13C-NMR spectrometer showed that the synthesis products compound is 5, 11, 17, 23, 29, 35-hexakis (p-tert-butyl)-37, 38, 39, 40, 41, 42-hexakis (ethoxy-carbonylmethoxy) calix[6]arene.

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References

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Published
2015-01-30
How to Cite
Dali, N., Wahab, A. W., Firdaus, F., & Maming, M. (2015). Sintesis Heksa-p-tert-Butilheksaesterkaliks[6]Arena dari p-tert-Butilkaliks[6]Arena. Al-Kimia, 3(1), 103-109. https://doi.org/10.24252/al-kimia.v3i1.1665
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