Synthesis and Characterization of UiO-66 as a Paracetamol Absorption Material

Fery Eko Pujiono, Try Ana Mulyati

Abstract


UiO-66 synthesis has been carried out by dissolving 0.53 grams of zirconium tetrachloride (ZrCl4) and 0.34 grams of Benzene-1,4-dicarboxylic Acid (H2BDC) in 30 mL Dimethylformamide (DMF). The solution is then distilled for 30 minutes and then heated in an oven at 140 ° C for 6 hours. The UiO-66 material produced was then characterized by an X-Ray Diffractometer (XRD) and Fourier Transform Infrared (FTIR). The results showed that the UiO-66 was successfully synthesized which supported the XRD results at 2θ 7.3o, 8.49o and 25.8o which were the peak characteristics of UiO-66. In addition, the FTIR results show a peak of around 1500 cm-1 showing vibrations of C = C on the benzene ring and a peak of about 1390 cm-1 indicating streching of O-C-O produced from the ligand. The peaks are around 750, and 660 cm-1 which indicates the presence of C-H vibrations from the ligand. UiO-66 was also approved as the adsorption agent of paracetamol which was approved with the highest adsorption of paracetamol at 72 hours immersion time which was 97.03%.


Keywords


Synthesis, UiO-66, Paracetamol, Adsorption

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References


Abid, H. R., Pham, G. H., Ang. H. M., Tade, M. O. and Wang, S. 2012. Adsorption of CH4 and CO2 on Zr-metal organic frameworks. Journal of Colloid and Interface Science, Vol.: 366, Hal.: 120–124

Chang, T., Wang, J., Ouyang, T., Zhang, Q., Jing, Y. 2015.

Photocatalytic Degradation of Acetaminophen in Aqueous Solutions by TiO2/ZSM-5 Zeolite with Low Energy Irradiation. Material Science and Engineering B. Vol.: 196. Hal.: 53-60.

Desale, A., Kamble, S. P., & Deosarkar, M. P. 2013. Photocatalytic Degradation of Paracetamol Using Degussa TiO2. Photocatalyst,International Journal of Chemical and Physical Sciences. Vo.: 2. Hal: 140-148.

Ilomuanya, M. O., Ohere, A. F., Zubair, S. A., Ubani-Ukoma, U. 2017. Evaluation of adsorption capacity of acetaminophen on activated charcoal dosage forms available in Nigeria by in vitro adsorption studies and scanning electron microscopy. Tropical Journal of Pharmaceutical Research. Vol.: 16(5). Hal.: 1105-1112.

Kandiah, M., Nilsen, M., H., Usseglio, S., Jakobsen, S., Olsbye, U. Tilset, M., larabi, C., Quadrelli, E. A., bonino, F., Lillerud, K. P. 2010. Synthesis and Stability of Tagged UiO-66 Zr-MOFs. Chemical Material. Vol.: 22. Hal.: 6632-6640.

Li, Q.L., Wang, J.P., Liu, W.C., Zhuang, X.Y., Liu, J.Q., Fan, G.L., Li, B.H., Lin, W.N., Man, J.H. 2015. A new (4,8)-connected topological MOF as potential drug delivery. Innorganic Chemistry Communication. Vol.: 55. Hal.: 8-10

Li, Z., Zhao, S., Wang, H., Peng, Y., Tan, Z., Tang, B. 2019. Functional Groups Influence and mechanism Research of UiO-66 type Metal Organic Frameworks for Ketoprofen Delivery. Colloids and Surface Biointerfaces. Vol.: 178. Hal.: 1-7.

Rahmawati, I. D., Ediati, R., Prasetyoko. 2014. Synthesis of UiO-66 Using Solvothermal Method at High Temperature. IPTEK Journal of Proceedings Series. Vol.: 1(1). Hal.: 42-47.

Schelling, M., Kim, M., Otal, E., Hinestroza, J. 2018. Decoration of Cotton Fibers with a Water-Stable Metal–Organic Framework (UiO-66) for the Decomposition and Enhanced Adsorption of Micropollutants in Water. Bioenginering. Vol.: 5(14). Hal.: 1-11.

Tai, S., Zhang, W., Zhang, J., Luo, G., Deng, M., Ling, Y., Jia, Y. 2016. Facile Preparation of UiO-66 Nanoparticles with Tunable Sizes in a Continuous flow Microreactor and Its Application in Drug Delivery. Microporous and Mesoporous Materials. Vol.: 220. Hal.: 148-154.

Trivedi, M. K., Patil, S., Shettigar, H., Bairwa, K. 2015. Effect of Biofield Treatment on Spectral Properties of Paracetamol and Piroxicam. Chemical Science Journal. Vol.: 6(3). Hal.: 1-6.

Wiratama, I. G. P., Ronaldi, H., Santoso, H. 2017. Pemodelan dan Simulasi Reaksi Degradasi Parasetamol Dengan Katalis TiO2. Jurnal Integrasi Proses. Vol.: 6(3). Hal.: 123 – 130.

Zhao, Q., yuan, W., Liang, J., Li, J. 2013. Synthesis and hydrogen storage studies of metal organic framework UiO-66. Hydrogen Energy. Vol.: 38(29) . Hal.: 1-6.




DOI: https://doi.org/10.24252/al-kimia.v7i2.10485

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