PEMBUATAN DAN KARAKTERISASI KOMPOSIT LiBOB/MgCl2 DENGAN METODE SOLID STATE REACTION

Arwin Darwis, Iswadi Iswadi, Sahara Sahara

Abstract


The manufacture and characterization of the lithium bus Composite (oxalate) borate with the addition of magnesium chloride (LiBOB/MgCl2). Electrolytes as a media transfer ion battery, plays an important role in the charge-discharge process of lithium ion batteries. The basic ingredients used in the study are lithium hydroxide (LIOH), Borid acid (H3BO3), Our acid dehydrate (H2C2O4 • 2H2O) and magnesium chloride hexahydrate (MgCl2 • 6H2O). The method used in this research is solid state reaction or known as solid-solid method. Based on the results of the XRD characterization, shows the peaks of LiBOB experiencing a shift after being added with 2.5%; 5% and 7.5% MgCl2 • 6H2O, in addition it also raises new peaks of magnesium. While the spread of the material is blown the sample appears evenly with the SEM-EDX test, however there are some elements that are experiencing clotting. And the FTIR test showed a change in the frequency of each mass increase of MgCl2 • 6H2O, but did not cause peak changes in each sample. In the EIS test results, obtaining a low electrical conductivity value, due to agglomeration of the material after the addition of elemental magnesium that is ionic. Thus also causes the diffusion of ions to lower.

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References


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DOI: https://doi.org/10.24252/jft.v6i1.12718

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